Cold-pressed fruit seed oils from blackcurrant, raspberry, and strawberry are gaining market share and – as relatively high value oils – are potential targets for adulteration. This study (open access) used identified 28 triacylglycerides (TAGs) as significant markers for distinguishing the 3 oils. These were identified from chemometric analysis of full tryglyceride profiles. Triglycerides were measured by ultra-high-performance liquid chromatography/quadrupole time-of-flight mass spectrometry. Lipidomic analysis identified 215 glycerides in the three oils. Chemometric analysis revealed that TAG profiles were superior to diacetylglyceride (DAG) profiles for oil differentiation and detecting adulteration. OPLS-DA identified 28 TAGs as significant markers for distinguishing the three oils.
The authors reported that comparison of glyceride profiles of pure and adulterated samples demonstrated that adulteration with 5 % or more sunflower or rapeseed oil could be detected. Targeted metabolomic analysis using specific markers for sunflower oil confirmed adulteration in raspberry and strawberry commercially purchased fruit seed oils.
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